Electricity and Magnetism > Magnetic Materials DCS# 5G30.20

PARAMAGNETISM OF LIQUID OXYGEN

paramagnetism of liquid oxygen

APPARATUS
strong C magnet or bar magnet
202-20-C
steel ball 202-20-D5
aluminum foil 202-02-E1
dewar 101-01-B
liquid nitrogen Science Center dock
camera 202-09-D
black cloth
202-01-C

DESCRIPTION
An aluminum foil cone is filled with liquid nitrogen.  Liquid oxygen condenses on the sides of the cone and drips between the poles of the magnet where it sticks until it evaporates.  Or use a strong bar magnet to deflect the stream of dripping oxygen.  Liquid nitrogen can be poured into the magnet gap to show that it is not paramagnetic.


NOTES
 
Place a steel ball bearing on one of the magnet poles to reduce the size of the gap.  Fold aluminum foil into a cone and fill with liquid nitrogen.

Hang the black cloth behind the magnet and/or illuminate the LO2 with a maglight for better visibility.
 
Boiling temperature of liquid oxygen is -183° C (90K).
Boiling temperature of liquid nitrogen is -196° C (77K).

Molecular orbital theory shows that the triplet state of O2 (with outer shell electron spins parallel) has a lower energy than the singlet state (with antiparallel spins forming part of a double bond).  So there are two unpaired electrons in molecular oxygen.

REFERENCES
Sutton, H-11, E-102.
Freier and Anderson, Es-3.